Activation and Catalytic Reactions of Saturated Hydrocarbons by A.E. Shilov, Georgiy B. Shul'pin, Alexander E. Shilov

By A.E. Shilov, Georgiy B. Shul'pin, Alexander E. Shilov

This monograph is dedicated to the activation and numerous changes of saturated hydrocarbons (alkanes), i.e. reactions followed by way of the C--H and C--C bond cleavage. Alkanes are the most components of oil and common fuel, and for this reason are the relevant feedstocks for the chemical undefined. however, those elements are identified to be the least reactive natural compounds. exact cognizance is paid to the lately chanced on alkane activations in the presence of steel complexes, that are defined in additional aspect. as well as the reactions of saturated hydrocarbons that are the major subject of this e-book, the activation of C--H bonds in arenes or even olefins and acetylenes are thought of. The monograph could be worthy not just should you have an interest in the activation of alkanes and different hydrocarbons by way of steel complexes, but in addition for experts in homogeneous and heterogeneous catalysis, petrochemistry, and organometallic chemistry. a few components of the monograph may be of curiosity for experts in inorganic and natural chemistry, theoretical chemistry, biochemistry or even biology, and additionally should you paintings within the petrochemical undefined, business natural synthesis and biotechnology.

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Evitt, E. ; Löffer, D. ; Wentrecek, P. ; Masuda, T. Science, 1993, 259, 340. ; Sen, A. J. Am. Chem. Soc. 1996, 118, 4574. 16. C. J. Am. Chem. Soc. 1979, 101, 1032. ; Hirobe, M. Heterocycles 1995, 40, 867. CHAPTER II HYDROCARBON TRANSFORMATIONS THAT DO NOT INVOLVE METALS OR THEIR COMPOUNDS n this chapter we will briefly survey the main types of hydrocarbon transformations that occur without the participation of solid metals or oxides and metal complexes. The alkane transformations described here should be taken into consideration for comparison when discussing the metal complex activation.

Theoretical Principles of Organic Chemistry, Khimiya: Leningrad, 1979, Chpts. 14, 15 (in Russian). (a) Taqui Khan, M. ; Martell, A. E. Homogeneous Catalysis by Metal Complexes; Vol. 1, Academic Press: New York, 1974, p. 143. (b) Walling, C. Acc. Chem. Res. 1975, 8, 125. (c) Karakhanov, E. ; Narin, S. ; Dedov, A. G. Appl. Organomet. Chem. 1990, 5, 445. (d) Ishii, Y. J. Mol. Catal. A: Chem. 1997, 117, 123. Shul’pin, G. ; Nizova, G. ; Shilov, A. E. J. Chem. , Chem. Commun. 1983, 671. Tyurina, L. ; Kombarova, S.

Chem. Soc. 1963, 85, 1544. ; Davidson, J. M. J. Chem. Soc.. 1965, 843. ; Verberg, G. Recl. Trav. Chim. Pays-Bas 1965, 84, 1263. ; Danno, S. et al. J. Am. Chem. Soc. 1969, 91, 7166. (c) Garnett, J. ; Hodges, R J. J. Am. Chem. Soc. 1967, 89, 4546. 19 20 References for Chapter I 10. Gol’dshleger, N. ; Tyabin, M. ; Shilov, A. ; Shteinman, A. A. Zh. Fiz. Khim. 1969, 43, 2174 (in Russian). 11. (a) Gol’dshleger, N. ; Es’kova, V. ; Shilov, A. ; Shteinman, A. A. Zh. Fiz. Khim. 1972, 46, 1353 (in Russian).

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